Woodhouseite

(repeating unit)CaAl3(SO4)(PO4)(OH)6IMA symbolWdh[1]Strunz classification8.BL.05Dana classification43.04.01.08Crystal systemTrigonalCrystal classHexagonal scalenohedral (3 2/m)Space groupR3m (no. 166)IdentificationFormula mass414.10 g/molColorWhite, flesh-pink or colorlessCrystal habitCrystals small, pseudocubic rhombohedral {1012}; tabular at times {0001}, with curved and striated faces.CleavageExcellent on {0001}Mohs scale hardness4.5LusterVitreous, pearly on {0001}StreakWhiteDiaphaneityTransparent to translucentSpecific gravity(measured): 3.012 (calculated): 3.00Optical propertiesUniaxial (+), 2V = 0° to 20°Refractive index(AM22) nω = 1.636
nε = 1.647Birefringenceδ = 0.011SolubilitySoluble in acids only after driving off the water in a closed tube.Other characteristicsNot radioactive.References[2][3][4]

Woodhouseite belongs to the beudantite group AB3(XO4)(SO4)(OH)6 where A = Ba, Ca, Pb or Sr, B = Al or Fe and X = S, As or P. Minerals in this group are isostructural with each other and also with minerals in the crandallite and alunite groups. They crystallise in the rhombohedral system with space group R3m and crystals are usually either tabular {0001} or pseudo-cubic to pseudo-cuboctahedral. Woodhouseite was named after Professor Charles Douglas Woodhouse[5] (1888–1975), an American mineralogist and mineral collector from the University of California, Santa Barbara, US, and one-time General Manager of Champion Sillimanite, Inc.

Environment

Woodhouseite is a secondary mineral found where wall rock alteration occurred in hydrothermal and disseminated ore deposits; rare in cave deposits, formed from guano. At the type locality it occurs in vugs in quartz veins in an andalusite, Al2OSiO4, deposit. This is in pre-Cambrian meta-quartzite that has been intruded by late Jurassic granitic rocks. Woodhouseite is found only near masses of lazulite, MgAl2(PO4)2(OH)2. Associated Minerals at the type locality include topaz, Al2SiO4F2, quartz, SiO2, augelite, Al2PO4(OH)3, lazulite, MgAl2(PO4)2(OH)2, tourmaline, baryte, BaSO4, muscovite, KAl2(Si3Al)O10(OH)2, and pyrophyllite, Al2Si4O10(OH)2, all of which formed before the woodhouseite, which is a late-forming mineral.[6]

Localities

The type locality is the Champion Mine (White Mountain Mine), White Mountain, Laws, White Mountains, Mono County, California, US. This is a former sillimanite mine located near Laws; mineralisation is a metamorphic sillimanite deposit hosted in quartzite.

Structure

Space Group: R3 2/m
Unit Cell Parameters: a = 6.993 Å, c = 16.386 Å, Z: 3

References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ "Woodhouseite Mineral Data".
  3. ^ http://www.mindat.org/min-4311.html Mindat.org
  4. ^ http://rruff.geo.arizona.edu/doclib/hom/woodhuseite.pdf Handbook of Mineralogy
  5. ^ "University of California: In Memoriam, May 1977".
  6. ^ Lemmon, Dwight M (1937) American Mineralogist 22:939-948