Nitride iodide

Class of chemical compounds

An iodide nitride is a mixed anion compound containing both iodide (I−) and nitride ions (N3−). Another name is metalloiodonitrides. They are a subclass of halide nitrides or pnictide halides.[1] Some different kinds include ionic alkali or alkaline earth salts, small clusters where metal atoms surround a nitrogen atom, layered group 4 element 2-dimensional structures (which could be exfoliated to a monolayer), and transition metal nitrido complexes counter-balanced with iodide ions. There is also a family with rare earth elements and nitrogen and sulfur in a cluster.

Related mixed-anion compounds include halogen variations: nitride fluoride, nitride chloride, and nitride bromide, and pnictogen variations phosphide iodide, arsenide iodide and antimonide iodides.

Production

Nitride iodides may be produced by heating metal nitrides with metal iodides. The ammonolysis process heats a metal iodide with ammonia.[2] A related method heats a metal or metal hydride with ammonium iodide. The nitrogen source could also be an azide or an amide.[2]

List

name formula formula
weight 		crystal
system 		space
group 		unit cell Å volume density comments ref
Li4NCl hexagonal R3 a=366.225 c=1977.18 Z=3 [3]
calcium nitride iodide Ca2NI P63/mmc a = 3.8095, c = 14.530, Z = 2 [4]
α-TiNI orthorhombic Pmmn a=3.941 b=3.51.5 c=8.955 Z=2 black [5]
NCr(I)(NiPr2)2 [6]
Cr(I)(N)(N(C(CD3)2CH3)(C6H3FMe))2 [7]
Zn2NI orthorhombic Pnma a=6.3590 b=6.2529 c=7.9549 <6 GPa [8]
strontium nitride iodide Sr2NI 316.15 trigonal R3m a = 4.0049 c = 23.055 Z=3 320.24 4.918 orange [9]
α-ZrNI orthorhombic Pmmn a=4.114 b=3.724 c=9.431 Z=2 orange [10][5]
β-ZrNI trigonal R3m a=3.718 c=31.381 Z=6 brown [5]
[(pcp)Mo(IV)(N)(I)][Na(15-crown-5)] pcp=C6H3(OPiPr2)2 [11]
Ba2NI
LiLa4N2I7 orthorhombic Pnma a = 13.7417, b = 12.1345, c = 10.7991 Z=4 @100K [12]
NaLa4N2I7 orthorhombic Pna21 a=14.0018 b=10.9315 c=12.1021 Z=4 5.361 colourless air sensitive [13]
Ce15N7I24 4245.6 orthorhombic Pnma a=12.060 b=32.216 c=16.360 Z=4 5.48 red; air sensitive [14]
NaCe4N2I7 orthorhombic Pna21 a=13.9703 b=10.8932 c=12.0194 Z=4 5.446 red air sensitive [13]
NaPr4N2I7 orthorhombic Pna21 a=13.9412 b=10.8578 c=11.9389 Z=4 5.524 yellowish green air sensitive [13]
NaNd4N2I7 orthorhombic Pna21 a=13.9135 b=10.86 c=11.86 Z=4 5.638 pinkish blue air sensitive [13]
(NdI2)3N [15]
(NdI2)3N(DME)4 [16]
NdI(S2N2)(THF) [17]
Nd3I5(S2N2)(S2)(THF)10 2088.72 monoclinic P21 a=12.393 b=43.389 c=12.684 β=90.013 Z=4 6820 2.034 yellow [15]
Ln3I5(S2)(S2N2)(THF)4(Phen)3 [18]
Ln3I5(S2)(S2N2)(THF)3(Py)7 [18]
(SmI)3N2(THF) [16]
ErI(S2N2)(THF) [17]
Nd2ErClI4-(S2)(S2N2)(THF)7 [17]
Nd2ErCl2I3(S2)(S2N2)(THF)7 [17]
(DyI2)3N [19]
Dy3I5(S2)(S2N2)(THF)10 [19]
Nd2DyI5(S2)(S2N2)(THF)7 [17]
Nd2DyI5(S3)(S2N2)(THF)9 2034.88 monoclinic P21/c a=23.1102 b=12.6551 c=23.8268 β =111.201 Z=4 6496.8 2.080 [20]
Nd2TbI5(S2)(S2N2)(THF)9 monoclinic P21/c a =23.1704 b =12.6340 c =23.8340, β =111.274° Z=4 [21]
Nd2TmI5(S2)(S2N2)(THF)9 monoclinic P21/c a =23.075 b =12.6540 c =23.809, β =111.460° Z=4 [21]
Nd2YbI5(S3)(S2N2)(THF)9 monoclinic P21/c a=23.0959 b=12.6632 c=23.8387 β =111.363 Z=4 6493.0 2.092 [20]
α-HfNI orthorhombic Pmmn a=4.10.67 b=3.6944 c=9.382 Z=2 [5][10]
β-HfNI trigonal R3m a=3.689 c=31.329 Z=6 brown [5]
ThNI tetragonal P4/nmm a=4.107 c=9.242 orange to golden grey [5][22]
UNI tetragonal P4/nmm a=3.99 c=9.20 Z=2 [5][23]

References

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  14. ^ Mattausch, Hansj Ürgen; Kremer, Reinhard K.; Simon, Arndt (April 1996). "Synthese, Kristallstruktur und magnetische Eigenschaften von Ce15N7I24". Zeitschrift für anorganische und allgemeine Chemie (in German). 622 (4): 649–654. doi:10.1002/zaac.19966220413. ISSN 0044-2313.
  15. ^ a b Fagin, A. A.; Fukin, G. K.; Cherkasov, A. V.; Shestakov, A. F.; Pushkarev, A. P.; Balashova, T. V.; Maleev, A. A.; Bochkarev, M. N. (2016). "Ln 3 I 5 (S 2 N 2 )(S 2 )(THF) 10 – a new type of molecular compounds". Dalton Transactions. 45 (11): 4558–4562. doi:10.1039/C5DT04742K. ISSN 1477-9226. PMID 26842841.
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  23. ^ Juza, R.; Meyer, W. (April 1969). "Über Uran-Nitrid-Chlorid, -Bromid und -Jodid". Zeitschrift für anorganische und allgemeine Chemie (in German). 366 (1–2): 43–50. doi:10.1002/zaac.19693660105. ISSN 0044-2313.
  • v
  • t
  • e
Salts and covalent derivatives of the iodide ion
HI
+H 		He
LiI BeI2 BI3
+BO3 		CI4
+C 		NI3
NH4I
+N 		I2O4
I2O5
I4O9 		IF
IF3
IF5
IF7 		Ne
NaI MgI2 AlI
AlI3 		SiI4 PI3
P2I4
+P
PI5 		S2I2 ICl
ICl3 		Ar
KI CaI2 ScI3 TiI2
TiI3
TiI4 		VI2
VI3 		CrI2
CrI3 		MnI2 FeI2
FeI3 		CoI2 NiI2
-Ni 		CuI ZnI2 GaI
GaI3 		GeI2
GeI4
+Ge 		AsI3
As2I4
+As 		Se IBr
IBr3 		Kr
RbI
RbI3 		SrI2 YI3 ZrI2
ZrI3
ZrI4 		NbI4
NbI5 		MoI2
MoI3 		TcI3 RuI3 RhI3 PdI2 AgI CdI2 InI
InI3 		SnI2
SnI4 		SbI3
+Sb 		TeI4
+Te 		I−
I−
3 		Xe
CsI
CsI3 		BaI2   LuI3 HfI3
HfI4 		TaI4
TaI5 		WI2
WI3
WI4 		ReI3
ReI
4 		OsI
OsI2
OsI3 		IrI3
IrI
4 		PtI2
PtI4 		AuI
AuI3 		Hg2I2
HgI2 		TlI
TlI3 		PbI2 BiI3 PoI2
PoI4 		AtI Rn
Fr RaI2   Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
↓
LaI2
LaI3 		CeI2
CeI3 		PrI2
PrI3 		NdI2
NdI3 		PmI3 SmI2
SmI3 		EuI2
EuI3 		GdI2
GdI3 		TbI3 DyI2
DyI
3 		HoI3 ErI3 TmI2
TmI3 		YbI2
YbI3
AcI3 ThI2
ThI3
ThI4 		PaI4
PaI5 		UI3
UI4 		NpI3 PuI3 AmI2
AmI3 		CmI3 BkI
3 		CfI
2
CfI
3 		EsI2
EsI3 		Fm Md No
  • v
  • t
  • e
Salts and covalent derivatives of the nitride ion
NH3
N2H4
+H
HN2−
H2N− 		He(N2)11
Li3N
LiN3 		Be3N2
Be(N3)2 		BN
-B 		C2N2
β-C3N4
g-C3N4
CxNy 		N2 NxOy
+O 		N3F
N2F2
N2F4
NF3
+F 		Ne
Na3N
NaN3 		Mg3N2
Mg(N3)2 		AlN Si3N4
-Si 		PN
P3N5
-P 		SxNy
SN
S2N2
S4N4
SN2H2 		NCl3
ClN3
+Cl 		Ar
K3N
KN3 		Ca3N2
Ca(N3)2 		ScN TiN
Ti3N4 		VN CrN
Cr2N 		MnxNy FexNy Co3N Ni3N Cu3N Zn3N2 GaN Ge3N4
-Ge 		AsN
+As 		Se4N4 Br3N
BrN3
+Br 		Kr
RbN3 Sr3N2
Sr(N3)2 		YN ZrN NbN β-Mo2N Tc Ru Rh PdN Ag3N Cd3N2 InN Sn SbN Te4N4? I3N
IN3
+I 		Xe
CsN3 Ba3N2
Ba(N3)2 		* LuN HfN
Hf3N4 		TaN WN RexNy Os Ir Pt Au Hg3N2 Tl3N (PbNH) BiN Po At Rn
Fr Ra3N2 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaN CeN PrN NdN PmN SmN EuN GdN TbN DyN HoN ErN TmN YbN
** Ac ThxNy PaN UxNy NpN PuN AmN CmN BkN Cf Es Fm Md No