Greenockite

(repeating unit)CdSIMA symbolGnk[1]Strunz classification2.CB.45Crystal systemHexagonalCrystal classDihexagonal pyramidal (6mm)
(same H-M symbol)Space groupP63mcUnit cella = 4.136
c = 6.713 [Å]; Z = 2StructureJmol (3D)Interactive imageIdentificationFormula mass144.48ColorHoney yellow, citron yellow, orange yellowCrystal habitColloform – forming from a gel or colloidal mass; encrustations – forms crust-like aggregates on matrix; radial – crystals radiate from a center without producing stellar forms (e.g. stibnite)TwinningRare on {1122} forming trillingsCleavageDistinct on {1122}, imperfect on {0001}FractureConchoidalTenacityBrittleMohs scale hardness3.0–3.5LusterAdamantine to resinousStreakYellow orange to brick redDiaphaneityNearly opaque to translucentSpecific gravity4.8–4.9Optical propertiesUniaxial (−)Refractive indexnω = 2.529 nε = 2.506Birefringenceδ = 0.023PleochroismWeakUltraviolet fluorescenceyellow-orange fluorescence under UV when rich in zinc[citation needed]Other characteristicsToxicReferences[2][3][4]

Greenockite, also cadmium blende or cadmium ochre (obsolete) is a rare cadmium bearing metal sulfide mineral consisting of cadmium sulfide (CdS) in crystalline form. Greenockite crystallizes in the hexagonal system. It occurs as massive encrustations and as hemimorphic six-sided pyramidal crystals which vary in color from a honey yellow through shades of red to brown. The Mohs hardness is 3 to 3.5 and the specific gravity is 4.8 to 4.9.

Greenockite belongs to the wurtzite group and is isostructural with it at high temperatures. It is also isostructural with sphalerite at low temperatures. It occurs with other sulfide minerals such as sphalerite and galena, and is the only ore mineral of cadmium. Most cadmium is recovered as a byproduct of copper, zinc, and lead mining. It is also known from the lead-zinc districts of the central United States.

It was first recognized in 1840 in Bishopton, Scotland, during the cutting of a tunnel for the Glasgow, Paisley and Greenock Railway. The mineral was named after the land owner Lord Greenock (1783–1859).[3][5]

Use

Greenockite, also known as "cadmium ochre", was used as a yellow pigment prior to cadmium being recognized as a toxic element. The extracted cadmium has various industrial use, such as electrical nickel-cadmium (NiCd) rechargeable batteries, electroplating, high temp alloys, plating steel and other metals that corrode easily, and use in control rods for some nuclear reactors.

References

  1. ^ Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi:10.1180/mgm.2021.43. S2CID 235729616.
  2. ^ Handbook of Mineralogy
  3. ^ a b Mindat
  4. ^ Webmineral
  5. ^ "Glasgow museum site". Archived from the original on 2012-07-16. Retrieved 2005-08-02.
  • Mineral galleries

External links

  • Media related to Greenockite at Wikimedia Commons
Crystal structure of greenockite
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