Borate sulfate

Mixed anion compound containing separate borate and sulfate anions

Borate sulfates are mixed anion compounds containing separate borate and sulfate anions. They are distinct from the borosulfates where the borate is linked to a sulfate via a common oxygen atom.

List

chem mw crystal system space group unit cell Å volume density comment references
sulfoborite Mg3(OH)[B(OH)4]2(SO4)F orthorhombic Pnma a=10.132 b=12.537 c=7.775 987.6 Biaxial (-) nα = 1.527 nβ = 1.536 nγ = 1.551

2V 79°

Max birefringence δ = 0.024

[1]
Heidornite Na2Ca3B5O8(OH)2(SO4)2Cl monoclinic C2/c a = 10.19, b = 7.76, c = 18.81

β = 93.33° Z=4

1,485 2.753 Biaxial (+) nα = 1.579 nβ = 1.588 nγ = 1.604

2V 63° to 77°

Max birefringence δ = 0.025

[2]
Charlesite Ca6Al(SO4)2B(OH)4(O,OH)12•26H2O trigonal P31c a = 11.161, c = 21.212 2,288 1.77 Uniaxial (-) nω = 1.492(3) nε = 1.475(3)

Max birefringence δ = 0.017

[3]
Vitimite Ca6B14O19(SO4)(OH)14•5H2O monoclinic P2/m a = 14.10, b = 19.53, c = 14.05 β = 120.39°=4 3,337 Biaxial (-) nα = 1.532(3) nβ = 1.537(1) nγ = 1.540(1)

Max birefringence δ = 0.008

[4]
Harkerite Ca12Mg4Al(BO3)3(SiO4)4(CO3)5 · H2O trigonal R3m a = 18.131 Å α = 33.46° 1,614 Uniaxial nα = 1.649 - 1.653 nβ = 1.649 - 1.653 [5]
Tatarinovite Ca3Al(SO4)[B(OH)4](OH)6 · 12H2O Hexagonal P63 a = 11.1110, c = 10.6294 1,136 1.79 colourless

Uniaxial (+) nω = 1.475 nε = 1.496

Max birefringence δ = 0.021

[6]
Sturmanite Ca6Fe3+2(SO4)2.5[B(OH)4](OH)12•25H2O trigonal P31c a = 11.16, c = 21.79 Z=2 2,350 yellow

Uniaxial (+/-) nω = 1.499 - 1.500 nε = 1.497 - 1.505

Max birefringence δ = 0.002

[7]
[Ni(atta)(SO4)0.5]·[B5O6(OH)4] 514.13 monoclinic P21/c a=9.0512 b=15.2776 c =15.0142, β=90.325° Z=4 2076.14 1.645 [8]
Buryatite Ca3(Si,Fe,Al)(SO4)[B(OH)4]O(OH)5 · 12H2O trigonal P31c a = 11.14, c = 20.99 Z=4 2,256 1.89 Uniaxial (-) nω = 1.523(3) nε = 1.532(3)

Max birefringence δ = 0.009

[9]
Rb3H(SO4)2(B2O3)2 hexagonal P63/m a = 6.502, c = 19.02 Z=2 2.803 [10]
Fontarnauite Na2Sr(SO4)B5O8(OH)•2H2O monoclinic P21/c a=6.458 b=22.299 c=8.571 β=103.05 Z=4 1,203 [11]
Y(SO4)[B(OH)4](H2O)·H2O triclinic P1 a=5.9679 b=6.8559 c=10.1698 α=79.608 β=76.673 γ=89.220 Z=2 398.02 2.502 [12]
Cs3H(SO4)2(B2O3)2 hexagonal P63/m a = 6.5648, c = 19.5669 Z = 2 3.322 [10]
La(SO4)[B(OH)4](H2O) 331.83 triclinic P1 a=6.2808 b=6.8321 c=8.6830 α=82.475 β=76.758 γ=87.300 Z=2 359.51 3.065 [12]
Pr(SO4)[B(OH)4](H2O)2 351.84 monoclinic P21/m a=6.2359 b=9.5542 c=6.8236 β=93.852 Z=2 405.64 2.881 [12]
Nd(SO4)[B(OH)4](H2O)2 355.17 monoclinic P21/m a=6.2119 b=9.5328 c=6.7923 β=93.755 Z=2 401.35 2.939 [12]
Sm(SO4)[B(OH)4](H2O) 343.27 triclinic P1 a=6.1467 b=6.7280 c=8.6068 α=81.769 β=76.653 γ=87.259 Z=2 342.71 3.326 [12]
Sm(SO4)[B(OH)4](H2O)2 361.30 monoclinic P21/m a=6.1601 b=9.5416 c=6.7589 β=93.816 Z=2 396.39 3.027 [12]
Eu(SO4)[B(OH)4](H2O) 344.88 triclinic P1 a=6.1205 b=6.7090 c=8.5844 α=81.713 β=76.680 γ=87.294 Z=2 339.40 3.375 [12]
Eu(SO4)[B(OH)4](H2O)2 362.89 monoclinic P21/m a=6.1322 b=9.5139 c=6.7343 β=93.683 Z=2 392.08 3.074 [12]
Gd(SO4)[B(OH)4](H2O)2 368.19 monoclinic P21/m a=6.1148 b=9.5078 c=6.7164 β=93.611 Z=2 389.70 3.138 [12]
Tb(SO4)[B(OH)4](H2O)·H2O 369.87 triclinic P1 a=6.0139 b=6.8972 c=10.1753 α=79.616 β=76.590 γ=89.106 Z=2 403.42 3.045 [12]
Dy(SO4)[B(OH)4](H2O)·H2O 373.43 triclinic P1 a=5.9880 b=6.8728 c=10.1638 α=79.652 β=76.597 γ=89.153 Z=2 400.12 3.100 [12]
Ho(SO4)[B(OH)4](H2O)·H2O 375.86 triclinic P1 a=5.9701 b=6.8570 c=10.1580 α=79.588 β=76.636 γ=89.193 Z=2 397.75 3.138 [12]
Er(SO4)[B(OH)4](H2O)·H2O 378.19 triclinic P1 a=5.9529 b=6.8401 c=10.1553 α=79.598 β=76.642 γ=89.198 Z=2 395.54 3.175 [12]
Tm(SO4)[B(OH)4](H2O)·H2O 379.86 triclinic P1 a=5.9289 b=6.8232 c=10.1422 α=79.531 β=76.663 γ=89.263 Z=2 392.40 3.215 [12]
Yb(SO4)[B(OH)4](H2O)·H2O 383.97 triclinic P1 a=5.9150 b=6.8090 c=10.1454 α=79.541 β=76.669 γ=89.243 Z=2 390.82 3.263 [12]
Lu(SO4)[B(OH)4](H2O)·H2O 385.91 triclinic P1 a=5.8992 b=6.7954 c=10.1322 α=79.551 β=76.691 γ=89.266 Z=2 388.53 3.299 [12]
Pb2[(BO2)(OH)](SO4) 570.26 monoclinic P21/m a=6.982 b=5.3917 c=8.167 β=98.643° 303.9 6.231 decompose 335 °C; band gap 4.08 [13]
Pb4(BO3)2(SO4) 1042.44 monoclinic P21/c a=6.9363 b=15.8784 c=9.6053 β=110.770° Z=4 989.15 7.000 melt 689 °C; band gap 4.03 eV [13][14]

References

  1. ^ "Sulfoborite". www.mindat.org. Retrieved 2020-12-15.
  2. ^ "Heidornite". www.mindat.org. Retrieved 2020-12-15.
  3. ^ "Charlesite". www.mindat.org. Retrieved 2020-12-15.
  4. ^ "Vitimite". www.mindat.org. Retrieved 2020-12-14.
  5. ^ "Harkerite". www.mindat.org. Retrieved 2020-12-14.
  6. ^ "Tatarinovite". www.mindat.org. Retrieved 2020-12-15.
  7. ^ "Sturmanite". www.mindat.org. Retrieved 2020-12-15.
  8. ^ Li, Wei; Deng, Yan-Ling; Pan, Chun-Yang (2022-05-11). "Structural Characterization and ORR Activity of a Copper Complex Borate and an Unexpected [Ni(atta)(SO 4 ) 0.5 ] + Borate-Sulfate". Inorganic Chemistry. 61 (20): 7787–7793. doi:10.1021/acs.inorgchem.2c00187. ISSN 0020-1669. PMID 35543612. S2CID 248695560.
  9. ^ "Buryatite". www.mindat.org. Retrieved 2020-12-15.
  10. ^ a b Daub, Michael; Hillebrecht, Harald (September 2015). "Borosulfates Cs 2 B 2 S 3 O 13 , Rb 4 B 2 S 4 O 17 , and A 3 HB 4 S 2 O 14 ( A = Rb, Cs) - Crystalline Approximants for Vitreous B 2 O 3 ?: Borosulfates Cs 2 B 2 S 3 O 13 , Rb 4 B 2 S 4 O 17 , and A 3 HB 4 S 2 O 14 ( A = Rb, Cs)". European Journal of Inorganic Chemistry. 2015 (25): 4176–4181. doi:10.1002/ejic.201500603.
  11. ^ Cooper, Mark A.; Hawthorne, Frank C.; García-Veigas, Javier; Alcobé, Xavier; Helvaci, Cahit; Grew, Edward S.; Ball, Neil A. (September 2015). "Fontarnauite, (Na,K) 2 (Sr,Ca)(SO 4 )[B 5 O 8 (OH)](H 2 O) 2 , A New Sulfate-Borate Mineral From Doğanlar (Emet), Kütahya Province, Western Anatolia, Turkey". The Canadian Mineralogist. 53 (5): 803–820. Bibcode:2015CaMin..53..803C. doi:10.3749/canmin.1400088. ISSN 0008-4476.
  12. ^ a b c d e f g h i j k l m n o p Wang, Wen-Wen; Xu, Xiang; Kong, Jin-Tao; Mao, Jiang-Gao (2018-01-02). "RE (SO 4 )[B(OH) 4 ](H 2 O), RE (SO 4 )[B(OH) 4 ](H 2 O) 2 , and RE (SO 4 )[B(OH) 4 ](H 2 O)·H 2 O: Rare-Earth Borate-Sulfates Featuring Three Types of Layered Structures". Inorganic Chemistry. 57 (1): 163–174. doi:10.1021/acs.inorgchem.7b02317. ISSN 0020-1669. PMID 29240405.
  13. ^ a b Ruan, Ting-Ting; Wang, Wen-Wen; Hu, Chun-Li; Xu, Xiang; Mao, Jiang-Gao (April 2018). "Pb4(BO3)2(SO4) and Pb2[(BO2)(OH)](SO4): New lead(II) borate-sulfate mixed-anion compounds with two types of 3D network structures". Journal of Solid State Chemistry. 260: 39–45. Bibcode:2018JSSCh.260...39R. doi:10.1016/j.jssc.2018.01.013.
  14. ^ Xie, Huiyuan; Wang, Fu; Liao, Biru; Liao, Xiaomin; Chen, Jiayu; Yu, Yang; Hou, Seng; Fan, Xiaoyun (September 2021). "A novel double anion layered photocatalyst Pb4(BO3)2SO4 with enhanced photocatalytic performance for antibiotic degradation". Chemical Engineering Journal. 429: 132344. doi:10.1016/j.cej.2021.132344. ISSN 1385-8947. S2CID 239660006.
  • v
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  • e
Borates
H3BO3 He
Li2B4O7 Be B +(CO3)
+(C2O4) 		(NH4)3BO3
+NO3 		O +F Ne
Na2[B4O5(OH)4]·8H2O
NaBO2
NaBO3
Na3BO3
Na2B8O13 		Mg3(BO3)2 AlBO3 Si -PO4
+PO4 		+S
-SO4
+SO4 		+Cl Ar
K2B4O7•4H2O
KB5O8•4H2O 		Ca3(BO3)2 ScBO3 TiBO3 -VO4 Cr Mn3(BO3)2 Fe3(BO3)2
FeBO3
FeB(OH)4 		Co3(BO3)2 Ni3(BO3)2 Cu3(BO3)2 Znx(BO3)x GaBO3
-GaO4 		-GeO4 -AsO4 -SeO4
-SeO3
+Se 		+Br Kr
Rb3BO3
RbB11O16(OH)2
Rb[B5O6(OH)4]•2H2O 		Sr3(BO3)2 YBO3 ZrB2O5 Nb Mo Tc Ru Rh Pd Ag3BO3 Cd3(BO3)2 InBO3 Sn -SbBO4 -TeO4
-TeO3 		+I Xe
Cs3BO3
CsB5O8•4H2O 		BaB2O4 * Lu3B5O12 HfB2O5 Ta W Re Os Ir Pt Au Hg Tl3BO3 Pb3(BO3)2 BiBO3 Po At Rn
Fr Ra ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* LaB3O6 CeB3O6 Pr4B10O21 NdBO3 Pm Sm Eu Gd Tb Dy4B6O15
Dy2B4O9 		Ho4B6O15
Ho2B4O9 		ErBO3 Tm3B5O12 Yb3B5O12
** Ac Th3(BO3)4 Pa U(BO3)2 Np Pu Am Cm Bk Cf[B6O8(OH)5] Es Fm Md No
  • v
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Compounds containing the sulfate group (SO2−4)
H2SO4 He
Li2SO4 BeSO4 B2S2O9
-BO3
+BO3 		esters
ROSO−3
(RO)2SO2
+CO3
+C2O4 		(NH4)2SO4
[N2H5]HSO4
(NH3OH)2SO4
NOHSO4
+NO3 		HOSO4 +F Ne
Na2SO4
NaHSO4 		MgSO4 Al2(SO4)3
Al2SO4(OAc)4 		Si +PO4 SO2−4
HSO3HSO4
(HSO4)2
+SO3 		+Cl Ar
K2SO4
KHSO4 		CaSO4 Sc2(SO4)3 TiOSO4 VSO4
V2(SO4)3
VOSO4 		CrSO4
Cr2(SO4)3 		MnSO4 FeSO4
Fe2(SO4)3 		CoSO4
Co2(SO4)3 		NiSO4
Ni2(SO4)3 		CuSO4
Cu2SO4
[Cu(NH3)4(H2O)]SO4 		ZnSO4 Ga2(SO4)3 Ge As +SeO3 Br Kr
RbHSO4
Rb2SO4 		SrSO4 Y2(SO4)3 Zr(SO4)2 Nb2O2(SO4)3 MoO(SO4)2
MoO2(SO4) 		Tc Ru(SO4)2 Rh2(SO4)3 PdSO4 Ag2SO4
AgSO4 		CdSO4 In2(SO4)3 SnSO4
Sn(SO4)2 		Sb2(SO4)3 Te +IO3 Xe
Cs2SO4
CsHSO4 		BaSO4 * Lu2(SO4)3 Hf Ta WO(SO4)2 Re2O5(SO4)2 OsSO4
Os2(SO4)3
Os(SO4)2 		IrSO4
Ir2(SO4)3 		Pt2(SO4)54– AuSO4
Au2(SO4)3 		Hg2SO4
HgSO4 		Tl2SO4
Tl2(SO4)3 		PbSO4
Pb(SO4)2 		Bi2(SO4)3 PoSO4
Po(SO4)2 		At Rn
Fr RaSO4 ** Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Nh Fl Mc Lv Ts Og
 
* La2(SO4)3 Ce2(SO4)3
Ce(SO4)2 		Pr2(SO4)3 Nd2(SO4)3 Pm2(SO4)3 Sm2(SO4)3 EuSO4
Eu2(SO4)3 		Gd2(SO4)3 Tb2(SO4)3 Dy2(SO4)3 Ho2(SO4)3 Er2(SO4)3 Tm2(SO4)3 Yb2(SO4)3
** Ac2(SO4)3 Th(SO4)2 Pa U2(SO4)3
U(SO4)2
UO2SO4 		Np(SO4)2 Pu(SO4)2 Am2(SO4)3 Cm2(SO4)3 Bk Cf2(SO4)3 Es Fm Md No